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(三氟甲基)三甲基硅烷
(Trifluoromethyl)trimethylsilane
基本信息
应用 | It is employed as a valuable reagent for trifluoromethylation of electrophilic substrates. It is also use an the nucleophilic addition of the trifluoromethyl group to aldehydes and ketones. It generates trifluoromethide with catalytic amounts of F- (TBAF or CsF) and reacts with carbonyl compounds to produce trifluoromethylated alcohols. |
备注 | Moisture sensitive. Store away from oxidizing agents and water/moisture. Keep the container tightly closed and place it in a cool, dry and well ventilated condition. Store under inert gas. |
MDL | MFCD00145454 |
EINECS | 000-000-0 |
分子式 | C4H9F3Si |
分子量 | 142.20 |
沸点 | 54-55° |
闪点 | -10°(14°F) |
密度 | 0.962 |
折射率 | 1.3305 |
灵敏度 | Moisture Sensitive. Ambient temperatures. |
形态 | Liquid |
溶解性 | Soluble in alcohol, THF, ether, dichloromethane, aromatic and aliphatic hydrocarbons. Soluble in water(with white smokes). |
Beilstein | 4241868 |
包装组 | II |
危险类别 | 11-36/37/38 Highly flammable.Irritating to eyes, respiratory system and skin. |
安全信息
危险等级 | 3 |
安全等级 | 9-16-23-26-33-37 Keep container in a well-ventilated place.Keep away from sources of ignition - No smoking.Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.Take precautionary measures against static discharges. |
欧盟危险品标志 | ![]() ![]() |
TSCA | 否 |
GHS危害和防范说明
GHS符号 | ![]() ![]() |
Hazard Statements | H225-H315-H319-H335 Highly flammable liquid and vapour.Causes skin irritation.Causes serious eye irritation.May cause respiratory irritation. |
Precautionary Statements | P210-P261-P303+P361+P353-P305+P351+P338-P405-P501a Keep away from heat/sparks/open flames/hot surfaces. - No smoking.Avoid breathing dust/fume/gas/mist/vapours/spray.IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.Store locked up.Dispose of contents/container in accordance with local/regional/national/international regulations. |